Formation of 2-Bromopropane: Addition to HBr to propene is an ionic electrophilic addition reaction in which the electrophile, (H+) adds to form a more stable 2° carbocation. In the 2nd reaction, the carbocation is rapidly attacked by the nucleophile (Br-) to form 2-bromopropane.
Formation of 1-Bromopropane:In the presence of benzoyl peroxide, the addition of HBr to propene involves free radical mechanism in which Br-free radical is obtained by the action of benzoyl peroxide on HBr.
(i) Br radical adds to propene to form the more stable 2° free radical.(ii) Free radical thus obtained rapidl